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2.two]decane core and defining the geometry of the exocyclic double bond. The activation energies of development of your vinyl-gold intermediates have been calculated and revealed a silyl enol ether with the unprotected indole moiety as a suitable precursor with the Toste cyclization. This 6-stage synthesis didn't require any nonstrategic redox man
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2.two]decane core and defining the geometry of your exocyclic double bond. The activation energies of formation from the vinyl-gold intermediates were calculated and uncovered a silyl enol ether by having an unprotected indole moiety as an acceptable precursor for your Toste cyclization. This six-stage synthesis did not require any nonstrategic red